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The second chapter deals with quantum chemical considerations, s, p, d and f orbitals, electronic configurations, Pauli's principle, spin-orbit coupling and levels, energy level diagrams, Hund's rules, Racah parameters, oxidation states, HSAB principle, coordination number, lanthanide contraction, interconfiguration fluctuations. This is followed by a chapter dealing with methods of determination of stability constants, stability constants of complexes, thermodynamic consideration, double-double effect, inclined w plot, applications of stability constant data.

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The fourth chapter deals with complexes of rare earth elements with a variety of complexing agents, such as monocarboxylic acids, dicarboxylic acids, polycarboxylic acids like citric, nitrilotriacetic, ethylenediamine tetraacetic; beta diketones, ligands with nitrogen donors, macrocyclic ligands, ligands with sulphur donors, phosphines, cyanate, thiocyanate, selenocyanate, perchlorate, decaborates, acyclic and macrocyclic Schiff's bases, carboranes, selenides and tellurides.

Structural chemistry of lanthanide complexes dealing with low coordination numbers, 6-, -7 and -8 coordination, dodecahedra, square antiprisms, hexagonal bipyramids, cubes and other structures, 9-coordination, high coordination numbers and organometallic structures is discussed in the fifth chapter. Kinetics and mechanisms complex formation involving rate expressions, rate laws, dissociative and associative pathways, techniques used in probing reaction mechanisms, crystal field effects are discussed in the following chapter. Crystal field theory, intensities of 4f-4f transitions, Judd-Ofelt theory of electric-dipole transitions, covalency model of hypersensitivity, dynamic coupling mechanism, solution spectra, spectral data for complexes, solvent effects, fluorescence and photochemistry of lanthanide complexes are dealt with in spectroscopy of lanthanide complexes.

The Global Race for Rare Earths

Photoelectron spectroscopy of rare earths involving typical spectra, core levels, splitting due to exchange, spin-orbit coupling, binding energies, states arising due to ionization of fn configuration, interconfiguration fluctuation and surface oxidation phenomena are discussed in the next chapter. The following chapter deals with the important topic of lanthanide NMR shift reagents and their applications in elucidating structures. The authors studied in schools headed by pioneers in rare earth chemistry, have a combined experience of years in inorganic chemistry, rare earth complex chemistry, nuclear and radiochemistry of rare earths and supramolecular chemistry.

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