I think it's more like "food" versus "foodstuffs" -- one is collective and always singular while the other is countable and plural. I suppose the singular of Kosmetika would be Kosmetikum but I don't think I've ever heard that. So they can both refer to cosmetics as a category - just that one refers to it as a whole, the other as individual objects taken together.
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Schminke is just one big part of make-up. Girls also use for example lipsticks Lippenstift, pl. Schminke is also used, when you paint a child on Helloween. Although less used, in English we have the single version, "cosmetic. You buy make-up, or cosmetics, at the cosmetics counter. A nose-job is cosmetic surgery.
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Insurance generally does not pay for cosmetic surgery in the United States. It doesn't pay for cosmetics either. I put "the beauty supplies" and got it wrong. The right answer was "the beauty culture".
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So, what is the use of "Kosmetik" here? Please correct me if I'm wrong: I would guess a lipstick would be "ein Kosmetikum"; several lipsticks would be "die Kosmetika"; cosmetic surgery would be "die Kosmetische Chirurgie"; and make-up stuff creams, powders, etc. I sure love being asked how something is spelled via sound when I haven't even learned the word yet.
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